ipmash@ipme.ru | +7 (812) 321-47-78
пн-пт 10.00-17.00
Институт Проблем Машиноведения РАН ( ИПМаш РАН ) Институт Проблем Машиноведения РАН ( ИПМаш РАН )

Institute for Problems in Mechanical Engineering
of the Russian Academy of Sciences

Institute for Problems in Mechanical Engineering of the Russian Academy of Sciences

About possibility of using the Roginsky-Schulz and Avrami-Erofeev equations in topokinetic analysis of carbothermic self-recovery of dispersed iron-graphite waste

Autors:
L.A. Dan, V.A. Maslov, L.A. Trofimova, S.B. Kargin, V. G. Artiukh, D.A. Kitaeva, N.V. Korihin ,
Pages:
111–119
Annotation:

Topokinetic analysis of experiment results on carbothermic self-healing of "wustite-graphite" dispersed samples particles was carried out. It was shown a dispersed iron-graphite waste contains metallic iron, iron oxide, carbon and impurities. Observations and calculations made in this work confirmed two-stage nature of process. The first initial stage of the process, at degrees of conversion less than 0.4, can be described by the Roginsky-Schulz or Avrami-Erofeev equations. Apparent activation energy of the initial stage of the process was calculated to be 141.34 kJ/mol. It was found that the Bell-Boudoir reaction is a limiting factor in the process.

File (pdf):
16:35
209
Используя этот сайт, вы соглашаетесь с тем, что мы используем файлы cookie.